Evidence for a seafloor rupture of the Carboneras Fault Zone (southern Spain): Relation to the 1522 Almería earthquake?     

Klaus Reicherter  Christian Hübscher 《Journal of Seismology》2007,11(1):15-26

High-resolution sea floor imaging (narrow beam sediment profiler) yields evidence for an offshore rupture along a strand of the Carboneras Fault Zone (CFZ) in the Gulf of Almería off southern Spain. The observed faults affect the seafloor and cut the Late Holocene sedimentary cover, hence the faults are regarded as active and the escarpments as relatively fresh. Seafloor faulting is associated with escarpments, fissures, pressure ridges, folds, and reverse faults indicating sinistral strike-slip faulting with a significant vertical displacement. Adjacent to the major fault zone secondary phenomena such as submarine slumps and slides are observed. The observed fresh escarpments imply an offshore rupture during a major earthquake along the CFZ. The southern Iberian margin and the Afro-Eurasian convergence zone form an area of moderate seismicity. However, some major events occurred, such as the 1522 Almería earthquake (EMS IX; [IGN (2005) Instituto Geografico Nacional, www.ign.es]), which affected large areas in the western Mediterranean. Different epicentral areas have been suspected, mainly along the 50 km long sinistral CFZ; however, no on-shore surface ruptures and paleoseismological evidences for this event have been found. Based on our data, a new epicentral area is proposed in the Gulf of Almería precisely along the observed sea floor rupture area, where the CFZ extend at least for 100 km offshore. Our findings suggest a specific seismic hazards and tsunami potential for offshore active and seismogenic faults in the Alborán Sea.  相似文献   

Local use of antibiotics and their input and fate in a small sewage treatment plant – significance of balancing and analysis on a local scale vs. nationwide scale     

Radka Alexy  Alexander Sommer  Frank T. Lange  Klaus Kümmerer 《洁净——土壤、空气、水》2006,34(6):587-592

Most antibiotics are only partially metabolised by patients before being discharged into the municipal sewage system along with patient excreta. Studies have shown that the majority of antibiotics pass through sewage treatment and are then released into the environment. Accordingly, investigations conducted in various countries have detected a number of antibiotics in the low μg or ng per litre range in different environmental compartments. Studies connecting mass balances of use on a local scale and of input and analysis of the antibiotic concentrations present in municipal sewage treatment plants are scarce. Data on local use of antibiotics and their relation to nationwide consumption are not available. This study investigated the use, input, and fate of antibiotics on a local scale and this data were compared with the German nationwide consumption. 42 antibiotics and 15 antimycotics were used in the mass balance consideration over a period of one year. It was found that the local pattern of usage differed only little from that found nationwide. Seasonal changes were minor and the concentrations actually measured were found to be in the expected range. Differences in both the identified occurrence and the concentrations of the target compounds were observed within and between the three sampling periods.  相似文献   

Synoptic hydrography of a highly stratified estuary     

Carlos Augusto França Schettini  Klaus Ricklefs  Eliane Cristina Truccolo  Volker Golbig 《Ocean Dynamics》2006,56(3-4):308-319

This study investigates the hydrodynamic characteristics of the lower, middle, and upper sectors of a highly stratified estuary, the Itajaí-Açu river estuary (south of Brazil ∼27° S/48.5° W). The study is based on a 25-h field campaign with three sampling stations positioned at 2, 17, and 38 km inward from the river mouth, during low river discharge condition and spring tide. The experimental data gathered was reduced and analyzed in terms of distribution of variables in time and space tide average vertical profiles and decomposition of the advective transport of salt and suspended particulate matter (SPM). Tidal range was nearly constant along the estuary, presenting time lag of about 2 h between lower and upper estuary. The ebb discharge peaks were about twice the discharge flood peaks and occurred simultaneously. The tide was the main determining agent in the lower estuary, where currents, salt stratification, and SPM distributions presented a repetitive behavior. In the middle estuary, the tide effects were also observed, but the presence of saline waters decreased along the time due to increasing river discharge during the campaign. The distribution of SPM in the mid- and upper estuary presented patched pattern not associated with tides and may be attributed to short-term flood contributions of tributaries. Currents presented ebb dominance in all three sectors; in the middle and upper estuary, they presented also a time asymmetry, with ebb currents longer than flood. The advective transport of salt in the lower estuary was upstream, with dominance of gravitational circulation term. In the mid-estuary, there was practically no transport, with balance between fluvial discharge (downstream) and tidal correlation (upstream). The advective transport of SPM was upstream in the lower estuary and downstream in the mid- and upper estuary, being dominated by gravitational circulation in the former and fluvial discharge in the others.  相似文献   

Quartz Rheology and Short-time-scale Crustal Instabilities     

Klaus Regenauer-Lieb  David A. Yuen 《Pure and Applied Geophysics》2006,163(9):1915-1932

We present numerical results of thermal-mechanical feedback in crustal quartz rheology and contrast this behavior to the vastly different character of an olivine mantle. In the numerical experiments quartz is found to have a very strong tendency for short-time-scale instabilities, while our numerical experiments show that olivine has a decisive tendency for a stable thermally lubricated slip. At the same time, olivine can also go through a transitional period of creep bursts, which are physically caused by multiple interacting ductile faults at various length and time scales which collocate quickly into a major shear zone. Since olivine has this strong propensity to self organize in a large apparently stable fault system, it lacks the dynamics of interacting ductile faults evident in other minerals. Quartz behaves totally different and keeps its jerky slip behavior for prolonged deformation. An example is shown here in which a 30 × 50 km piece of a wet quarzitic crust is extended for about 2 Ma. The associated total displacement field clearly shows the unstable slipping events, which have a characteristic time frame of one to several years, In contrast, olivine is very stable and has a much longer time scale for thermal instability of 100 kyrs.  相似文献   

Measurement and investigation of chamber radical sources in the European Photoreactor (EUPHORE)     

Judit Zádor  Tamás Turányi  Klaus Wirtz  Michael J. Pilling 《Journal of Atmospheric Chemistry》2006,55(2):147-166

It is essential to quantify the background reactivity of smog-chambers, since this might be the major limitation of experiments carried out at low pollutant concentrations typical of the polluted atmosphere. Detailed investigation of three chamber experiments at zero-NO _x in the European Photoreactor (EUPHORE) were carried out by means of rate-of-production analysis and two uncertainty analysis tools: local uncertainty analysis and Monte Carlo simulations with Latin hypercube sampling. The chemical mechanism employed was that for methane plus the inorganic subset of the Master Chemical Mechanism (MCMv3.1). Newly installed instruments in EUPHORE allowed the measurement of nitrous acid and formaldehyde at sub-ppb concentrations with high sensitivity. The presence of HONO and HCHO during the experiments could be explained only by processes taking place on the FEP Teflon walls. The HONO production rate can be described by the empirical equation W(HONO)_EUPHORE ^dry = a × j _{NO 2}× exp (− T ₀/T) in the low relative humidity region (RH < 2%, a = 7.3×10²¹ cm⁻³, T ₀ = 8945K), and by the equation W(HONO)_EUPHORE ^humid = W(HONO)_EUPHORE ^dry+ j _{NO 2}× b × RH ^q in the higher relative humidity region (2% < RH < 15%, b = 5.8×10⁸ cm⁻³ and q = 0.36, and RH is the relative humidity in percentages). For HCHO the expression W(HCHO)_EUPHORE = c × j _{NO 2}exp (− T′₀/T) is applicable (c = 3.1×10¹⁷ cm⁻³ and T′₀ = 5686 K). In the 0–15% relative humidity range OH production from HONO generated at the wall is about a factor of two higher than that from the photolysis of 100 ppb ozone. Effect of added NO₂ was found to be consistent with the dark HONO formation rate coefficient of MCMv3.1.  相似文献   

Crustal Provenance and Cooling of the Basement Complexes of the Sierra de San Luis: An Insight Into the Tectonic History of the Pro to-Andean Margin of Gondwana   总被引：1，自引：0，他引：1  

Andr Steenken  Klaus Werner  Mnica G. Lopez de Luch  Siegfried Siegesmund  Sabine Pawlig 《Gondwana Research》2004,7(4):1171-1195

The Sierra de San Luis constitutes the southernmost tip of the Eastern Sierras Pampeanas. Its Palaeozoic metamorphic basement units define a key location for the understanding of the accretional history along the proto-Andean margin of Gondwana. Although, it is largely accepted that the polyphase accretional history of the Sierras Pampeanas is preluded by the docking of the Pampean Terrane followed by the Famatinian Orogenic Cycle that involves subduction along the margin of Gondwana and the accretion of the Precordillera (Cuyania) Terrane and finally ceased with the collision of the Chilenia terrane, a vast amount of controversial information concerning the timing and mode of collisions as well as the origin of the different involved crustal fragments within the Eastern Sierras Pampeanas is published. In this paper, those different hypothesis are presented and evaluated under the light of new isotopic data of the Sierra de San Luis. Nd-systematics of the metasedimentary sequences of the Sierra de San Luis indicate that the studied sequences were developed on the Pampean Terrane. An Amazonian origin of the Pampean Terrane that was probably detached from the Arequipa Antofalla Craton is proposed. Furthermore, the correlation of two low-grade phyllitic belts (San Luis Formation) with the widespread Puncoviscana Formation is not supported by Sm-Nd data. It is suggested that the sedimentary precursors of the Pringles Metamorphic Complex and the topping phyllites were sourced on the Pampean Orogen and accommodated in a newly formed back arc basin during the early Famatinian.

The cooling history of the basement complex is recorded by an extensive amount of K-Ar muscovite and biotite ages. A high variability in muscovite ages is only partly related to different intrusion times of two pegmatoid generations. Post Famatinian to Achalian crustal scale mylonite formation (-359 Ma) and a rotational exhumation of the central basement unit are causal for the observed K-Ar muscovite age pattern in the range from 395 Ma to 447 Ma. Therefore, the decrease in metamorphic degree from west to east is the result of the erosion level of a crustal profile from the mid lower crust to the upper crust. An even higher variability in K-Ar biotite cooling ages covering the range from 315 Ma to 418 Ma is related to the slow cooling after the Famatinian Orogenic Cycle or reheating during the Achalian Orogenic Cycle and consequent variable reset of the isotopic system. However, ages recorded by biotite booklets substantiate the hypothesis of a differential exhumation of the basement of the Sierra de San Luis.  相似文献   

Pb/Pb and U/Pb zircon dating of subvolcanic rhyolite as a time marker for Hercynian granite magmatism and Sn mineralisation in the Eibenstock granite, Erzgebirge, Germany: Considering effects of zircon alteration   总被引：1，自引：0，他引：1  

Ulf Kempe  Klaus Bombach  Dmitrij Matukov  Thomas Schlothauer  Jan Hutschenreuter  Dieter Wolf  Sergej Sergeev 《Mineralium Deposita》2004,39(5-6):646-669

Tin mineralisation is closely related to rhyolite stocks and dykes which occur in the endo- and exocontact of the Eibenstock granite, Erzgebirge, Germany. The same structures which cut the granite control the rhyolite emplacement and the location of ore-bearing greisen bodies. Albitisation and greisenisation related to tin mineralisation as well as sericitisation and argillic alteration may be traced by changes in chemical and mineralogical composition of both rhyolite and granite wall rock. Comprehensive zircon studies by scanning electron microscopy (secondary and backscattered electron as well as cathodoluminescence imaging; EDX measurements) reveal that zircon from rhyolite and from the enclosing granite shows significant changes in chemical composition and crystallinity, including distortion of the U-Pb isotope system when affected by greisenisation. Single evaporation analysis of zircon from rhyolite with little or no greisenisation gave a ²⁰⁷Pb/²⁰⁶Pb age of 290±5 Ma, whereas zircon from little altered granite gave a ²⁰⁷Pb/²⁰⁶Pb age of 320±8 Ma. The single evaporation age of zircon from rhyolite is confirmed by ²³⁸U/²⁰⁶Pb SHRIMP ages of 297±8 Ma. The significant time gap of at least 20 Ma between granite intrusion and rhyolite formation suggests that the late magmatic evolution of the Eibenstock granite cannot be regarded as a source for tin-ore forming fluids as previously assumed.  相似文献   

Immiscible separation of metalliferous Fe/ Ti-oxide melts from fractionating alkali basalt: P-T-f O2 conditions and two-liquid elemental partitioning     

Vratislav Hurai  Klaus Simon  Uwe Wiechert  Jochen Hoefs  Patrik Konečný  Monika Huraiová  Jacques Pironon  Jozef Lipka 《Contributions to Mineralogy and Petrology》1998,133(1-2):12-29

Globules of iron-dominated (59–69 wt% FeO_tot) and titanium-dominated (43.5 wt% TiO₂) oxide melts have been detected in igneous xenoliths from Pliocene-to-Pleistocene alkali basalts of the Western Carpathians. Fluid inclusion and mineral composition data indicate immiscible separation of the high-iron-oxide melt (HIM) at magmatic temperatures. The HIM separation occurred during clinopyroxene (augite) accumulation in an alkali trachybasalt and continued during crystallization of amphibole (kaersutite) and K-feldspar (anorthoclase), the latter coexisting with trachyte and alkalic rhyolite residual melts. Some HIM was also expelled from sub-alkalic rhyolite (70–77% SiO₂), coexisting with An_27–45 plagioclase and quartz in granitic (tonalite-trondhjemite) xenoliths. Oxygen fugacities during HIM separation range from −1.4 to +0.6 log units around the QFM buffer. A close genetic relationship between HIM-hosted xenoliths and mantle-derived basaltic magma is documented by mineral ¹⁸O values ranging from 4.9 to 5.9‰ V-SMOW. δD values of gabbroic kaersutite between −61 and −86‰ V-SMOW are in agreement with a presumed primary magmatic water source. Most trace elements, except Li, Rb and Cs, have preferentially partitioned into the HIM. The HIM/Si-melt partition coefficients for transition elements (Sc, V, Cr, Co, Ni) and base metals (Zn, Cu, Mo) are between 2–160, resulting in extreme enrichment in the HIM. La and Ce also concentrate in the silicic melt, whereas Tb-Tm in the HIM. Hence, the immiscible separation causes REE fractionation and produces residual silicic melt enriched in LREE and depleted in HREE. The weak fractionation among Tb-Tm and Yb, Lu can be attributed to recurrent extraction of the HIM from the magmatic system, while flat HREE chondrite-normalized patterns are interpreted to indicate no or little loss of the HIM. Received: 30 September 1997 / Accepted: 23 March 1998  相似文献   

Fractionation of dissolved organic matter affected by polyvalent metal cations     

Klaus Kaiser 《Organic Geochemistry》1998,28(12):849-854

The purpose of the study was to evaluate the influence of polyvalent cations known to form complexes with natural organic substances on the operational fractionation of dissolved organic matter (DOM) using XAD-8 adsorber resin. Dissolved organic matter solutions from a forest floor were treated with increasing concentrations of polyvalent metal cations (Ca²⁺, Al³⁺, Fe³⁺) at different pH levels. Then the concentrations of total dissolved organic carbon (DOC) and the distribution between hydrophilic and hydrophobic DOC were determined. The concentrations of total DOC decreased slightly when the C/metal ratio was less than 10, especially for Al and Fe. Hydrophilic DOC increased and hydrophobic DOC decreased with increasing concentrations of metal cations. Effects increased in the order Ca<Al<Fe and were more pronounced at low DOC concentrations and high pH values. The reason for the reduction of the DOC concentrations seemed to be the formation of insoluble metal–DOM complexes, while soluble metal–DOM complexes may induce an alteration of the distribution between hydrophilic and hydrophobic DOC. Thus, the polyvalent cations and their concentration need to be considered when DOM fraction distributions, determined with XAD-8 resin, of different waters are compared, especially at low DOC contents and high pH.  相似文献   

Bruthabitatmodellierung für den Drosselrohrsänger (Acrocephalus arundinaceus L.) als Bestandteil eines integrativen Managementsystems für Seeufer     

Annette Woithon  Klaus Schmieder 《Limnologica》2004,34(1-2):132

Within the context of the European legislative (e.g. Water Framework Directive, Natura 2000 network) monitoring and assessment of wetland areas are of great significance. This research points out the relevance of spatially explicit habitat models as an essential part of a decision support system for lake shore management. The Great Reed Warbler (Acrocephalus arundinaceus L.) was selected as a key species of aquatic reed structures. Many results of investigation about breeding behaviour of this German Red List species are available. The factors of selecting a breeding range were modelled in a Geographic Information System (GIS) using indices that quantify the corresponding spatial characteristics of patches in the ecosystem (e.g. shape complexity or distance to other vegetation structures). A habitat suitability map was created for a nature conservation area at Lake Constance, Germany. The observed breeding places in the investigation area showed a great coincidence with the modelled habitat ranges. This modelling approach of integrating spatial indicators is an important basis to provide automated monitoring systems based on remote sensing methods.  相似文献